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About: Borane carbonyl     Goto   Sponge   NotDistinct   Permalink

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Type: Thingdul:ChemicalObjectchemical substanceChemical compoundchemical compound New Facet based on Instances of this Class

Borane carbonyl is the inorganic compound with the formula H3BCO. This colorless gas is the adduct of borane and carbon monoxide. It is usually prepared by combining borane-ether complexes and CO. The compound is mainly of theoretical and pedagogical interest. It reacts with aqueous base to give boranocarbonate H3BCO22−. Bond distances are B−C, 1.529; C−O, 1.140; 1.194 Å. The H−B−H angle is 113.7°. The CO vibrational band is at 2165 cm−1, 22 cm−1 higher than that of free CO.