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About: Danishefsky's diene     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : umbel-rc:ChemicalSubstanceType, within Data Space : dbpedia.demo.openlinksw.com associated with source document(s)

Type: Thingdul:ChemicalObjectchemical substanceChemical compoundyago:WikicatOrganosiliconCompoundsyago:Abstraction100002137yago:Cognition100023271yago:Compound105870180yago:Concept105835747yago:Content105809192yago:Element114840755yago:Idea105833840yago:Matter100020827yago:Part113809207yago:PhysicalEntity100001930yago:PsychologicalFeature100023100yago:Quintessence114847103yago:Relation100031921chemical compoundyago:Substance100019613yago:Whole105869584yago:WikicatEthersumbel-rc:ChemicalSubstanceType New Facet based on Instances of this Class

Danishefsky's diene (Kitahara diene) is an organosilicon compound and a diene with the formal name trans-1-methoxy-3-trimethylsilyloxy-buta-1,3-diene named after Samuel J. Danishefsky. Because the diene is very electron-rich it is a very reactive reagent in Diels-Alder reactions. This diene reacts rapidly with electrophilic alkenes, such as maleic anhydride. The methoxy group promotes highly regioselective additions. The diene is known to react with amines, aldehydes, alkenes and alkynes. Reactions with imines and nitro-olefins have been reported.