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Dihydroxylation is the process by which an alkene is converted into a vicinal diol. Although there are many routes to accomplish this oxidation, the most common and direct processes use a high-oxidation-state transition metal (typically osmium or manganese). The metal is often used as a catalyst, with some other stoichiometric oxidant present. In addition, other transition metals and non-transition metal methods have been developed and used to catalyze the reaction.

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  • Dihydroxylation (en)
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  • Dihydroxylation is the process by which an alkene is converted into a vicinal diol. Although there are many routes to accomplish this oxidation, the most common and direct processes use a high-oxidation-state transition metal (typically osmium or manganese). The metal is often used as a catalyst, with some other stoichiometric oxidant present. In addition, other transition metals and non-transition metal methods have been developed and used to catalyze the reaction. (en)
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  • http://commons.wikimedia.org/wiki/Special:FilePath/Dihydroxylation.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Hydroxylation_in_the_Synthesis_of_Brassinosteroid.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/NMO_vs_TMEDA.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Osmium_Dihydroxylation_Mechanism.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Prevost-Woodward_Modification.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Prevost_Reaction.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Prevost_and_Woodward_First_Steps.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Prevost_and_Woodward_Scheme.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Sharpless_Asymmetric_Dihydroxylation_Mnemonic.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Sugar_synthesis.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/TMEDA_Transition_State.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Woodward_Reaction.png
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  • Dihydroxylation is the process by which an alkene is converted into a vicinal diol. Although there are many routes to accomplish this oxidation, the most common and direct processes use a high-oxidation-state transition metal (typically osmium or manganese). The metal is often used as a catalyst, with some other stoichiometric oxidant present. In addition, other transition metals and non-transition metal methods have been developed and used to catalyze the reaction. (en)
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