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About: Flyover complex     Goto   Sponge   NotDistinct   Permalink

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In organometallic chemistry, a flyover complex features two metals bridged by the fragment OC(RC=CR)2. Some flyover complexes are symmetrical and some are not. Common examples are the iron carbonyl derivatives, which are typically air-stable, soluble in nonpolar solvents, and red-orange in color. These diiron complexes arise by the reaction of alkynes with iron carbonyls. Such reactions are known to generate many products, e.g. complexes of cyclopentadienones and para-quinones.