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About: Kharasch addition     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : yago:WikicatFreeRadicalReactions, within Data Space : dbpedia.demo.openlinksw.com associated with source document(s)

Type: yago:WikicatNameReactionsyago:WikicatOrganicReactionsyago:ChemicalProcess113446390yago:ChemicalReaction113447361yago:NaturalProcess113518963yago:PhysicalEntity100001930yago:Process100029677diseaseyago:WikicatFreeRadicalReactions New Facet based on Instances of this Class

The Kharasch addition is an organic reaction and a metal-catalysed free radical addition of CXCl3 compounds (X = Cl, Br, H) to alkenes. The reaction was discovered by Morris S. Kharasch in the 1940s. The basic reaction scheme runs as follows: R2C=CH2 + R'X → R2CX-CH2R': and proceeds through the CXCl2 free radical. Examples of organohalides are carbon tetrachloride and chloroform. The addition is an anti-Markovnikov addition. Early work linked the addition to olefin polymerization and is therefore considered a first step into what was to become atom transfer radical polymerization.