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About: LISICON     Goto   Sponge   NotDistinct   Permalink

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Type: Thingcompany New Facet based on Instances of this Class

LISICON is an acronym for LIthium Super Ionic CONductor, which refers to a family of solids with the chemical formula Li2+2xZn1−xGeO4. The first example of this structure was discovered in 1977 with , providing a chemical formula of Li14Zn(GeO4)4. The crystal structure of LISICON consists of a network of [Li11Zn(GeO4)4]3- as well as 3 loosely bonded Li+. The weaker bonds allow for the lithium ions to easily move from site to site, not needing to break strong bonds to do so. Also, this structure forms large “bottlenecks” between the interstitial positions which these ions occupy, additionally lowering the energy required to move from site to sit. These two factors allow for the lithium ions to diffuse quickly and easily through the structure. However, because of the shape of the channels