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About: Metal-catalyzed σ-bond rearrangement     Goto   Sponge   NotDistinct   Permalink

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The metal ion-catalyzed σ-bond rearrangement is a collection of chemical reactions that occur with highly strained organic compounds are treated with metal ions like Ag+, Rh(I), or Pd(II) based reagents. [2+2] ring openings are sometimes observed: These rearrangements proceed via oxidative addition of strained rings. Such processes are related to the activation of cyclopropanes by transition metals.