The nitridosilicates are chemical compounds that have anions with nitrogen bound to silicon. Counter cations that balance the electric charge are mostly electropositive metals from the alkali metals, alkaline earths or rare earth elements. Silicon and nitrogen have similar electronegativities, so the bond between them is covalent. Nitrogen atoms are arranged around a silicon atom in a tetrahedral arrangement. Related compounds include pnictogenidosilicates :phosphidosilicates, arsenidosilicates and ; pnictogenidogernamates: . By replacing silicon, there are also nitridogermanates, , and .
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