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Potassium trispyrazolylborate, commonly abbreviated KTp, is the potassium salt of the trispyrazolylborate ligand. KTp is a white crystalline solid which is soluble in polar solvents, alcohols, and water. The synthesis of KTp involves potassium borohydride and pyrazole without a solvent. KBH4 + 3 pzH → KTp + 3 H2 The tris(pyrazolyl)borate forms octahedral coordination compounds with the formula M[Tp]2 with first row transition metals. KTp also forms 1:1 complexes, for example it can be converted to K[TpMo(CO)3]; KTp+Mo(CO)6→K[TpMo(CO)3 ]+ 3CO K[TpMo(CO)3]+ BuONO→TpMo(CO)2NO+CO+KOBu

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  • Potassium trispyrazolylborate (en)
  • 三吡唑基硼氢化钾 (zh)
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  • 三吡唑基硼氢化钾是一种化合物，化学式为C9H10BKN6，可简写为KTp。它是白色晶体，可溶于极性有机溶剂，如醇、水等。它可由硼氢化钾和吡唑反应制得，反应不需要溶剂。 KBH4 + 3 pzH → KTp + 3 H2 它可以和第一行的过渡金属反应，得到八面体配合物MTp2。它也可以形成1:1的配合物，如： KTp+Mo(CO)6→K[TpMo(CO)3 ]+ 3CO K[TpMo(CO)3]和亚硝酸正丁酯反应，得到中性的橙色配合物TpMo(CO)2NO。 K[TpMo(CO)3]+ BuONO→TpMo(CO)2NO+CO+KOBu (zh)
  • Potassium trispyrazolylborate, commonly abbreviated KTp, is the potassium salt of the trispyrazolylborate ligand. KTp is a white crystalline solid which is soluble in polar solvents, alcohols, and water. The synthesis of KTp involves potassium borohydride and pyrazole without a solvent. KBH4 + 3 pzH → KTp + 3 H2 The tris(pyrazolyl)borate forms octahedral coordination compounds with the formula M[Tp]2 with first row transition metals. KTp also forms 1:1 complexes, for example it can be converted to K[TpMo(CO)3]; KTp+Mo(CO)6→K[TpMo(CO)3 ]+ 3CO K[TpMo(CO)3]+ BuONO→TpMo(CO)2NO+CO+KOBu (en)
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  • Potassium trispyrazolylborate.svg (en)
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  • Potassium triboranuide (en)
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  • Potassium trispyrazolylborate, commonly abbreviated KTp, is the potassium salt of the trispyrazolylborate ligand. KTp is a white crystalline solid which is soluble in polar solvents, alcohols, and water. The synthesis of KTp involves potassium borohydride and pyrazole without a solvent. KBH4 + 3 pzH → KTp + 3 H2 The tris(pyrazolyl)borate forms octahedral coordination compounds with the formula M[Tp]2 with first row transition metals. KTp also forms 1:1 complexes, for example it can be converted to K[TpMo(CO)3]; KTp+Mo(CO)6→K[TpMo(CO)3 ]+ 3CO When K[TpMo(CO)3] is treated with butyl nitrite it yields the neutral orange complex TpMo(CO)2NO. K[TpMo(CO)3]+ BuONO→TpMo(CO)2NO+CO+KOBu (en)
  • 三吡唑基硼氢化钾是一种化合物，化学式为C9H10BKN6，可简写为KTp。它是白色晶体，可溶于极性有机溶剂，如醇、水等。它可由硼氢化钾和吡唑反应制得，反应不需要溶剂。 KBH4 + 3 pzH → KTp + 3 H2 它可以和第一行的过渡金属反应，得到八面体配合物MTp2。它也可以形成1:1的配合物，如： KTp+Mo(CO)6→K[TpMo(CO)3 ]+ 3CO K[TpMo(CO)3]和亚硝酸正丁酯反应，得到中性的橙色配合物TpMo(CO)2NO。 K[TpMo(CO)3]+ BuONO→TpMo(CO)2NO+CO+KOBu (zh)
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  • Potassium tri(1H-pyrazol-1-yl)boranuide (en)
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