Rotational correlation time is the average time it takes for a molecule to rotate one radian. In solution, rotational correlation times are in the order of picoseconds. For example, the 1.7 ps for water, and 100 ps for a pyrroline nitroxyl radical in a DMSO-water mixture. Rotational correlation times are employed in the measurement of microviscosity (viscosity at the molecular level) and in protein characterization.
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