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About: Rotational temperature     Goto   Sponge   NotDistinct   Permalink

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The characteristic rotational temperature (θR or θrot) is commonly used in statistical thermodynamics to simplify the expression of the rotational partition function and the rotational contribution to molecular thermodynamic properties. It has units of temperature and is defined as where is the rotational constant, I is a molecular moment of inertia, h is the Planck constant, c is the speed of light, ħ = h/2π is the reduced Planck constant and kB is the Boltzmann constant.