About: Transition metal oxo complex

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A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as bridging ligands (Fig. 1). Oxo ligands stabilize high oxidation states of a metal. They are also found in several metalloproteins, for example in molybdenum cofactors and in many iron-containing enzymes. One of the earliest synthetic compounds to incorporate an oxo ligand is potassium ferrate (K2FeO4), which was likely prepared by Georg E. Stahl in 1702.

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rdf:type	yago:WikicatOxides yago:Abstraction100002137 yago:Chemical114806838 yago:Compound114818238 yago:Material114580897 yago:Matter100020827 yago:Oxide114971519 yago:Part113809207 yago:PhysicalEntity100001930 yago:Relation100031921 comics character yago:Substance100019613
rdfs:label	Oxokomplexy kovů (cs) Complexe oxo (fr) Transition metal oxo complex (en)
rdfs:comment	A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as bridging ligands (Fig. 1). Oxo ligands stabilize high oxidation states of a metal. They are also found in several metalloproteins, for example in molybdenum cofactors and in many iron-containing enzymes. One of the earliest synthetic compounds to incorporate an oxo ligand is potassium ferrate (K2FeO4), which was likely prepared by Georg E. Stahl in 1702. (en) Un complexe oxo est un complexe métallique dont un ligand est l'anion bidenté oxyde O2−, généralement pontant, parfois terminal. Ce ligand stabilise les états d'oxydation élevés des cations métalliques. On le trouve dans diverses métalloprotéines, comme les cofacteurs molybdoptérine et FeMoco (« cofacteur à fer et molybdène »), ainsi que dans de nombreuses enzymes contenant du fer. L'un des premiers composés synthétiques contenant un ligand oxo est sans doute le ferrate de potassium K2FeO4, probablement préparé par le chimiste allemand Georg Ernst Stahl dès 1702. (fr)
foaf:depiction
dcterms:subject	Ligands Transition metal oxides
Wikipage page ID	29811008 (xsd:integer)
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Link from a Wikipage to another Wikipage	Potassium ferrate Potassium permanganate Pyridinium chlorochromate Metallate C-H bond activation Biochemistry Biodiversity Cytochrome P450 DMSO reductase Water oxidation catalysis Ligands Organic chemistry Oxide Georg Ernst Stahl dbr:Molybdopterin Coordination complex Heme Polyoxometalate Transition metal oxides Sulfite oxidase Alpha-ketoglutarate-dependent hydroxylases Bridging ligand Nitrogenase Osmium tetroxide Diol Aldehyde ferredoxin oxidoreductase Cofactor (biochemistry) Dimethyl sulfide Dimethyl sulfoxide Group (periodic table) Methane monooxygenase Catalytic oxidation Vicinal (chemistry) Olation Molybdenum cofactor Molybdenum oxotransferase Photosystem II Oxygen-evolving complex Oxygen cycle Metal-ligand multiple bond Metalloproteins Dioxygen complex Ketoglutarate Pyridinium dichromate Oxophilic
sameAs	Transition metal oxo complex Transition metal oxo complex Transition metal oxo complex Transition metal oxo complex Transition metal oxo complex Transition metal oxo complex
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has abstract	Un complexe oxo est un complexe métallique dont un ligand est l'anion bidenté oxyde O2−, généralement pontant, parfois terminal. Ce ligand stabilise les états d'oxydation élevés des cations métalliques. On le trouve dans diverses métalloprotéines, comme les cofacteurs molybdoptérine et FeMoco (« cofacteur à fer et molybdène »), ainsi que dans de nombreuses enzymes contenant du fer. L'un des premiers composés synthétiques contenant un ligand oxo est sans doute le ferrate de potassium K2FeO4, probablement préparé par le chimiste allemand Georg Ernst Stahl dès 1702. * Ligand oxo (a) pontant, (b) terminal. (fr) A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers, i.e. it can exist as a terminal or (most commonly) as bridging ligands (Fig. 1). Oxo ligands stabilize high oxidation states of a metal. They are also found in several metalloproteins, for example in molybdenum cofactors and in many iron-containing enzymes. One of the earliest synthetic compounds to incorporate an oxo ligand is potassium ferrate (K2FeO4), which was likely prepared by Georg E. Stahl in 1702. (en)
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is rdfs:seeAlso of	Aldehyde ferredoxin oxidoreductase
is Link from a Wikipage to another Wikipage of	Oxohalide 18-electron rule Stephen J. Lippard Oxo ligand

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