About: Triiron dodecacarbonyl     Goto   Sponge   NotDistinct   Permalink

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Triiron dodecarbonyl is the organoiron compound with the formula Fe3(CO)12. It is a dark green solid that sublimes under vacuum. It is soluble in nonpolar organic solvents to give intensely green solutions. Most low-nuclearity clusters are pale yellow or orange. Hot solutions of Fe3(CO)12 decompose to an iron mirror, which can be pyrophoric in air.The solid decomposes slowly in air, and thus samples are typically stored cold under an inert atmosphere. It is a more reactive source of iron(0) than iron pentacarbonyl.

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  • Dodekakarbonyl triželeza (cs)
  • Trieisendodecacarbonyl (de)
  • Dodécacarbonyle de trifer (fr)
  • Triferro dodecacarbonile (it)
  • Додекакарбонилтрижелезо (ru)
  • Triiron dodecacarbonyl (en)
  • 十二羰基三铁 (zh)
rdfs:comment
  • Dodekakarbonyl triželeza je anorganická sloučenina se vzorcem Fe3(CO)12. Jedná se o tmavě zelenou pevnou látku, za nízkého tlaku sublimující, rozpustnou v nepolárních rozpouštědlech. Horké roztoky Fe3(CO)12 se rozkládají za tvorby vrstvy železa, která může být samozápalná. K pomalému rozkladu dochází na vzduchu i za běžných teplot, roztoky se tak obvykle skladují za nízkých teplot a/nebo nepřítomnosti vzduchu. Jedná se o reaktivnější zdroj železa než pentakarbonyl. (cs)
  • Trieisendodecacarbonyl ist eines der drei bekannten, stabilen Carbonyle des Eisens. Es ist eine tiefgrüne Substanz, die bei 140 °C unter Zersetzung schmilzt. (de)
  • Il triferro dodecacarbonile o ferro dodecacarbonile è il composto chimico di formula Fe3(CO)12. Fu uno dei primi cluster metallocarbonile a essere sintetizzato. È una fonte di ferro(0) più reattiva del ferro pentacarbonile. Il composto è disponibile in commercio. (it)
  • Triiron dodecarbonyl is the organoiron compound with the formula Fe3(CO)12. It is a dark green solid that sublimes under vacuum. It is soluble in nonpolar organic solvents to give intensely green solutions. Most low-nuclearity clusters are pale yellow or orange. Hot solutions of Fe3(CO)12 decompose to an iron mirror, which can be pyrophoric in air.The solid decomposes slowly in air, and thus samples are typically stored cold under an inert atmosphere. It is a more reactive source of iron(0) than iron pentacarbonyl. (en)
  • Додекакарбонилтрижелезо — неорганическое соединение, карбонильный комплекс железа с формулой Fe3(CO)12,тёмно-зелёные кристаллы,не растворяется в воде,окисляется на воздухе. (ru)
  • 十二羰基三铁 (英語:Triiron dodecacarbonyl),分子式为Fe3(CO)12。它是第一种人工合成的金属-羰基簇合物。相比五羰基铁的化学性质更活泼,更易于分解为单质铁。 (zh)
  • Le dodécacarbonyle de trifer, généralement appelé trifer dodécacarbonyle par anglicisme, est un composé chimique de formule Fe3(CO)12. Il s'agit d'un carbonyle de métal constitué de 12 groupes carbonyle CO et de trois centres fer Fe. Il se présente sous la forme d'un solide vert foncé qui se sublime dans le vide. Il se dissout dans les solvants apolaires pour donner des solutions d'un vert intense. Il se décompose lentement dans l'air et est pour cette raison stocké à froid sous atmosphère inerte. C'est une source de fer plus réactive que le pentacarbonyle de fer Fe(CO)5. (fr)
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  • http://commons.wikimedia.org/wiki/Special:FilePath/Fe3(CO)12lessFe-Fe.png
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