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Magnetization transfer (MT), in NMR and MRI, refers to the transfer of nuclear spin polarization and/or spin coherence from one population of nuclei to another population of nuclei, and to techniques that make use of these phenomena. There is some ambiguity regarding the precise definition of magnetization transfer, however the general definition given above encompasses all more specific notions. NMR active nuclei, those with non-zero spin, can be energetically coupled to one another under certain conditions. The mechanisms of nuclear-spin energy-coupling have been extensively characterized and are described in the following articles: Angular momentum coupling, Magnetic dipole–dipole interaction, J-coupling, Residual dipolar coupling, Nuclear Overhauser effect, Spin–spin relaxation, and Sp

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  • Magnetization transfer (en)
  • 磁化の移動 (ja)
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  • 核磁気共鳴における磁化の移動(じかのいどう)または分極移動とは、あるスピンから別のスピンへ磁化が移動する現象のことである。 磁化移動を用いたNMR分析法の代表例を以下に示す。 * 核オーバーハウザー効果:磁気双極子相互作用による。 * 交差分極(CP):固体中の磁気双極子相互作用を利用した、回転座標系での磁化移動。 * INEPT:スピン結合を利用して1Hの磁化を13Cや15Nへ移動させる方法。溶液で用いられる。 * :INEPTを改良したもの。 (ja)
  • Magnetization transfer (MT), in NMR and MRI, refers to the transfer of nuclear spin polarization and/or spin coherence from one population of nuclei to another population of nuclei, and to techniques that make use of these phenomena. There is some ambiguity regarding the precise definition of magnetization transfer, however the general definition given above encompasses all more specific notions. NMR active nuclei, those with non-zero spin, can be energetically coupled to one another under certain conditions. The mechanisms of nuclear-spin energy-coupling have been extensively characterized and are described in the following articles: Angular momentum coupling, Magnetic dipole–dipole interaction, J-coupling, Residual dipolar coupling, Nuclear Overhauser effect, Spin–spin relaxation, and Sp (en)
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  • Magnetization transfer (MT), in NMR and MRI, refers to the transfer of nuclear spin polarization and/or spin coherence from one population of nuclei to another population of nuclei, and to techniques that make use of these phenomena. There is some ambiguity regarding the precise definition of magnetization transfer, however the general definition given above encompasses all more specific notions. NMR active nuclei, those with non-zero spin, can be energetically coupled to one another under certain conditions. The mechanisms of nuclear-spin energy-coupling have been extensively characterized and are described in the following articles: Angular momentum coupling, Magnetic dipole–dipole interaction, J-coupling, Residual dipolar coupling, Nuclear Overhauser effect, Spin–spin relaxation, and Spin saturation transfer. Alternatively, some nuclei in a chemical system are labile and exchange between non-equivalent environments. A more specific example of this case is presented in the section Chemical Exchange Magnetization transfer. In either case, magnetization transfer techniques probe the dynamic relationship between two or more distinguishable nuclei populations, in so far as energy exchange between the populations can be induced and measured in an idealized NMR experiment. (en)
  • 核磁気共鳴における磁化の移動(じかのいどう)または分極移動とは、あるスピンから別のスピンへ磁化が移動する現象のことである。 磁化移動を用いたNMR分析法の代表例を以下に示す。 * 核オーバーハウザー効果:磁気双極子相互作用による。 * 交差分極(CP):固体中の磁気双極子相互作用を利用した、回転座標系での磁化移動。 * INEPT:スピン結合を利用して1Hの磁化を13Cや15Nへ移動させる方法。溶液で用いられる。 * :INEPTを改良したもの。 (ja)
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