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Triphenylstibine is the chemical compound with the formula Sb(C6H5)3. Abbreviated SbPh3, this colourless solid is often considered the prototypical organoantimony compound. It is used as a ligand in coordination chemistry and as a reagent in organic synthesis. Like the related molecules triphenylphosphine and triphenylarsine, SbPh3 is pyramidal with a propeller-like arrangement of the phenyl groups. The Sb-C distances average 2.14-2.17 Å and the C-Sb-C angle are 95°. SbPh3 was first reported in 1886, being prepared from antimony trichloride by the reaction:

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  • Triphenylstibine (en)
  • Трифенилсурьма (ru)
  • 三苯基䏲 (zh)
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  • Трифенилсурьма — элементоорганическое вещество, простейшее арилпроизводное сурьмы с формулой Sb(C6H5)3, бесцветные кристаллы, не растворяется в воде, устойчивы на воздухе. (ru)
  • 三苯基䏲是一种有机锑化合物，化学式为Sb(C6H5)3。它可以缩写为SbPh3。这种无色固体通常被认为是有机锑化合物的原型。它在配位化学中用作配体，有机合成中用作试剂。 SbPh3最早于1886年由三氯化锑制得： 6 Na + 3 C6H5Cl + SbCl3 → (C6H5)3Sb + 6 NaCl 现在使用格氏试剂，由苯基溴化镁与SbCl3反应制得。 (zh)
  • Triphenylstibine is the chemical compound with the formula Sb(C6H5)3. Abbreviated SbPh3, this colourless solid is often considered the prototypical organoantimony compound. It is used as a ligand in coordination chemistry and as a reagent in organic synthesis. Like the related molecules triphenylphosphine and triphenylarsine, SbPh3 is pyramidal with a propeller-like arrangement of the phenyl groups. The Sb-C distances average 2.14-2.17 Å and the C-Sb-C angle are 95°. SbPh3 was first reported in 1886, being prepared from antimony trichloride by the reaction: (en)
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  • Triphenylstibine (en)
name
  • Triphenylstibine (en)
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  • http://commons.wikimedia.org/wiki/Special:FilePath/Triphenylstibine-3D-balls.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Triphenylstibine_crystals.jpg
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  • Ball-and-stick model of the triphenylstibine molecule (en)
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  • Triphenylstibine-3D-balls.png (en)
  • Triphenylstibine_crystals.jpg (en)
OtherNames
  • Triphenylantimony (en)
PIN
  • Triphenylstibane (en)
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  • changed (en)
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  • Triphenylstibine is the chemical compound with the formula Sb(C6H5)3. Abbreviated SbPh3, this colourless solid is often considered the prototypical organoantimony compound. It is used as a ligand in coordination chemistry and as a reagent in organic synthesis. Like the related molecules triphenylphosphine and triphenylarsine, SbPh3 is pyramidal with a propeller-like arrangement of the phenyl groups. The Sb-C distances average 2.14-2.17 Å and the C-Sb-C angle are 95°. SbPh3 was first reported in 1886, being prepared from antimony trichloride by the reaction: 6 Na + 3 C6H5Cl + SbCl3 → (C6H5)3Sb + 6 NaCl An alternative method treats phenylmagnesium bromide with SbCl3. (en)
  • Трифенилсурьма — элементоорганическое вещество, простейшее арилпроизводное сурьмы с формулой Sb(C6H5)3, бесцветные кристаллы, не растворяется в воде, устойчивы на воздухе. (ru)
  • 三苯基䏲是一种有机锑化合物，化学式为Sb(C6H5)3。它可以缩写为SbPh3。这种无色固体通常被认为是有机锑化合物的原型。它在配位化学中用作配体，有机合成中用作试剂。 SbPh3最早于1886年由三氯化锑制得： 6 Na + 3 C6H5Cl + SbCl3 → (C6H5)3Sb + 6 NaCl 现在使用格氏试剂，由苯基溴化镁与SbCl3反应制得。 (zh)
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alternative name
  • Triphenylantimony (en)
IUPAC name
  • Triphenylstibane (en)
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