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Free molecular flow describes the fluid dynamics of gas where the mean free path of the molecules is larger than the size of the chamber or of the object under test. For tubes/objects of the size of several cm, this means pressures well below 10−3 mbar. This is also called the regime of high vacuum, or even ultra-high vacuum. This is opposed to viscous flow encountered at higher pressures. The presence of free molecular flow can be calculated, at least in estimation, with the Knudsen number (Kn). If Kn > 10, the system is in free molecular flow, also known as Knudsen flow.

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