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Statements

Subject Item
dbr:Bis(diphenylphosphinoethyl)phenylphosphine
rdf:type
dbo:ChemicalCompound dbo:ChemicalSubstance n12:ChemicalObject wikidata:Q11173 owl:Thing
rdfs:label
Bis(diphenylphosphinoethyl)phenylphosphine Bis-(2-difenilfosfinoetil)-fenilfosfina
rdfs:comment
La bis-(2-difenilfosfinoetil)-fenilfosfina è una fosfina tridentata usata nella chimica organometallica. Viene di solito indicata con il nome comune triphos. In condizioni normali è un solido cristallino di colore bianco, insolubile in acqua ma solubile in solventi organici.La molecola ha simmetria molecolare Cs. Bis(diphenylphosphinoethyl)phenylphosphine is the organophosphorus compound with the formula [Ph2PCH2CH2]2PPh (Ph = C6H5). It is an air-sensitive white solid that function as tridentate ligands in coordination and organometallic chemistry. It is prepared by the free-radical-catalysed addition of phenylphosphine to vinyldiphenylphosphine: 2 Ph2PCH=CH2 + H2PPh → [Ph2PCH2CH2]2PPh It can bind to an octahedral metal center give either a facial or meridional isomers. Some derivatives are square planar complexes of the type [MX(triphos)]+ (M = Ni, Pd, Pt; X = halide).
foaf:depiction
n7:LinearTriphos.png
dct:subject
dbc:Chelating_agents dbc:Phenyl_compounds dbc:Tridentate_ligands dbc:Tertiary_phosphines
dbo:wikiPageID
48326106
dbo:wikiPageRevisionID
1118578329
dbo:wikiPageWikiLink
dbr:Tripodal_ligand dbr:1,1,1-Tris(diphenylphosphinomethyl)ethane dbr:Phenylphosphine dbc:Phenyl_compounds dbr:Coordination_chemistry dbr:Diethylenetriamine dbc:Tridentate_ligands dbr:Organometallic_chemistry dbc:Tertiary_phosphines dbr:Tridentate dbr:Organophosphorus_compound dbr:Vinyldiphenylphosphine dbr:Ligand dbc:Chelating_agents
owl:sameAs
dbpedia-it:Bis-(2-difenilfosfinoetil)-fenilfosfina n16:3MKfE wikidata:Q3640387
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dbt:Chembox_Properties dbt:Chembox_Hazards dbt:Chembox_Identifiers dbt:Chembox dbt:Stdinchicite dbt:P-phrases dbt:Fdacite dbt:Chemspidercite dbt:Cascite dbt:H-phrases dbt:GHS07
dbo:thumbnail
n7:LinearTriphos.png?width=300
dbp:imagefile
LinearTriphos.png
dbp:iupacname
Bisphenylphosphine
dbp:othernames
Triphos
dbp:verifiedfields
changed
dbp:verifiedrevid
430033015
dbp:watchedfields
changed
dbo:abstract
La bis-(2-difenilfosfinoetil)-fenilfosfina è una fosfina tridentata usata nella chimica organometallica. Viene di solito indicata con il nome comune triphos. In condizioni normali è un solido cristallino di colore bianco, insolubile in acqua ma solubile in solventi organici.La molecola ha simmetria molecolare Cs. Bis(diphenylphosphinoethyl)phenylphosphine is the organophosphorus compound with the formula [Ph2PCH2CH2]2PPh (Ph = C6H5). It is an air-sensitive white solid that function as tridentate ligands in coordination and organometallic chemistry. It is prepared by the free-radical-catalysed addition of phenylphosphine to vinyldiphenylphosphine: 2 Ph2PCH=CH2 + H2PPh → [Ph2PCH2CH2]2PPh It can bind to an octahedral metal center give either a facial or meridional isomers. Some derivatives are square planar complexes of the type [MX(triphos)]+ (M = Ni, Pd, Pt; X = halide).
prov:wasDerivedFrom
wikipedia-en:Bis(diphenylphosphinoethyl)phenylphosphine?oldid=1118578329&ns=0
dbo:wikiPageLength
3257
dbo:alternativeName
Triphos
dbo:iupacName
Bis(diphenylphosphinoethyl)phenylphosphine
foaf:isPrimaryTopicOf
wikipedia-en:Bis(diphenylphosphinoethyl)phenylphosphine