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Statements

Subject Item
dbr:Heteroborane
rdf:type
dbo:MeanOfTransportation
rdfs:label
Heteroborane
rdfs:comment
Heteroboranes are classes of boranes, at least one boron atom is replaced by another element. Like many of the related boranes, these clusters are polyhedra and are similarly classified as closo-, nido-, arachno-, hypho-, according to the so-called electron count. Closo- represents a complete polyhedron, while nido-, arachno- and hypho- stand for polyhedrons that are missing one, two and three vertices.
dcterms:subject
dbc:Boranes dbc:Cluster_chemistry dbc:Boron_compounds
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49028503
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1117510248
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dbr:Polyhedra dbr:Polyhedral_skeletal_electron_pair_theory dbr:Dodecaborate dbc:Boron_compounds dbr:Carborane dbr:Boranes dbr:Boron dbc:Cluster_chemistry dbr:Azaborane dbc:Boranes
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dbo:abstract
Heteroboranes are classes of boranes, at least one boron atom is replaced by another element. Like many of the related boranes, these clusters are polyhedra and are similarly classified as closo-, nido-, arachno-, hypho-, according to the so-called electron count. Closo- represents a complete polyhedron, while nido-, arachno- and hypho- stand for polyhedrons that are missing one, two and three vertices. Structurally, various heteroboranes can be derived from the icosahedral (Ih) B12H122– via formal replacement of its BH fragments with isoelectronic CH+, P+ or S2+ fragments, e.g. closo-1-CB11H12–, closo-1,2-C2B10H12, closo-1,2-P2B10H10 or closo-1-SB11H11.
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wikipedia-en:Heteroborane