. . . . . . "5857"^^ . . "Barton-Decarboxylierung"@de . . "Bartonova dekarboxylace je radik\u00E1lov\u00E1 organick\u00E1 reakce, p\u0159i n\u00ED\u017E se karboxylov\u00E9 kyseliny p\u0159em\u011B\u0148uj\u00ED thiohydroxam\u00E1tov\u00E9 estery (b\u011B\u017En\u011B naz\u00FDvan\u00E9 Bartonovy estery) a produkt je n\u00E1sledn\u011B zah\u0159\u00EDv\u00E1n za p\u0159\u00EDtomnosti radik\u00E1lov\u00E9ho inici\u00E1toru a zdroje vod\u00EDku za vzniku dekarboxylovan\u00E9ho produktu. Jde o p\u0159\u00EDklad reduk\u010Dn\u00ED dekarboxylace. Jej\u00ED pomoc\u00ED lze od\u0161t\u011Bpit karboxylov\u00E9 skupiny z alkylov\u00FDch skupin a nahradit je jin\u00FDmi. Tuto reakci objevil britsk\u00FD chemik Derek Barton."@cs . . "yes"@en . . . . . "La r\u00E9action de Barton-Motherwell (ou d\u00E9carboxylation de Barton-Motherwell) est une s\u00E9quence r\u00E9actionnelle permettant d'effectuer s\u00E9lectivement une r\u00E9duction d'un acide carboxylique en alcane. Elle fut mise au point par Sir Derek Harold Richard Barton (Prix Nobel de chimie 1969) et Willie B. Motherwell. Son m\u00E9canisme est similaire \u00E0 celui de la r\u00E9action de d\u00E9oxyg\u00E9nation de Barton-McCombie."@fr . . . . . "Bartonova dekarboxylace je radik\u00E1lov\u00E1 organick\u00E1 reakce, p\u0159i n\u00ED\u017E se karboxylov\u00E9 kyseliny p\u0159em\u011B\u0148uj\u00ED thiohydroxam\u00E1tov\u00E9 estery (b\u011B\u017En\u011B naz\u00FDvan\u00E9 Bartonovy estery) a produkt je n\u00E1sledn\u011B zah\u0159\u00EDv\u00E1n za p\u0159\u00EDtomnosti radik\u00E1lov\u00E9ho inici\u00E1toru a zdroje vod\u00EDku za vzniku dekarboxylovan\u00E9ho produktu. Jde o p\u0159\u00EDklad reduk\u010Dn\u00ED dekarboxylace. Jej\u00ED pomoc\u00ED lze od\u0161t\u011Bpit karboxylov\u00E9 skupiny z alkylov\u00FDch skupin a nahradit je jin\u00FDmi. Tuto reakci objevil britsk\u00FD chemik Derek Barton."@cs . . . "La r\u00E9action de Barton-Motherwell (ou d\u00E9carboxylation de Barton-Motherwell) est une s\u00E9quence r\u00E9actionnelle permettant d'effectuer s\u00E9lectivement une r\u00E9duction d'un acide carboxylique en alcane. Elle fut mise au point par Sir Derek Harold Richard Barton (Prix Nobel de chimie 1969) et Willie B. Motherwell. Son m\u00E9canisme est similaire \u00E0 celui de la r\u00E9action de d\u00E9oxyg\u00E9nation de Barton-McCombie."@fr . . "La Descarboxilaci\u00F3n de Barton es una reacci\u00F3n org\u00E1nica en la que previamente un \u00E1cido carbox\u00EDlico se convierte en una 1-aciloxipiridina (Funcionalmente es un \u00E9ster hidrox\u00E1mico com\u00FAnmente conocido como \u00E9ster de Barton). El producto se calienta en presencia de un iniciador de radicales y un donante de hidr\u00F3geno apropiado para completar la descarboxilaci\u00F3n reductiva del \u00E1cidos carbox\u00EDlico inicial.\u200B\u200B Esta reacci\u00F3n permite extraer el grupo carboxilo de un \u00E1cido de tal manera que el grupo alquilo sea sustituido con otros grupos funcionales.\u200B\u200B (ver esquema 1) Esta reacci\u00F3n debe su nombre al qu\u00EDmico brit\u00E1nico y Premio Nobel Derek Barton (1918-1998)."@es . . "Substitution reaction"@en . "29655812"^^ . "Bartonova dekarboxylace"@cs . "\u5DF4\u987F\u8131\u7FA7\u53CD\u5E94\u662F\u4E00\u79CD\u81EA\u7531\u57FA\u53CD\u5E94\uFF0C\u8BE5\u53CD\u5E94\u4E2D\u7FA7\u9178\u5148\u88AB\u8F6C\u5316\u4E3A\u786B\u4EE3\u5F02\u7F9F\u809F\u9178\u916F\uFF08\u901A\u5E38\u79F0\u4E3A\u5DF4\u987F\u916F\uFF09\u3002\u7136\u540E\u518D\u5728\u81EA\u7531\u57FA\u5F15\u53D1\u5242\u548C\u5408\u9002\u7684\u8FD8\u539F\u6027\u6C22\u4F9B\u4F53\u5B58\u5728\u4E0B\u5BF9\u4EA7\u7269\u8FDB\u884C\u52A0\u70ED\uFF0C\u8FDB\u800C\u53EF\u4EE5\u5F97\u5230\u8131\u7FA7\u540E\u7684\u4EA7\u7269\u3002 \u5DF4\u987F\u8131\u7FA7\u53CD\u5E94\u662F\u4E00\u79CD\u8FD8\u539F\u8131\u7FA7\u53CD\u5E94\u3002\u5229\u7528\u8BE5\u53CD\u5E94\uFF0C\u53EF\u4EE5\u4ECE\u6709\u673A\u7269\u4E2D\u8131\u53BB\u7FA7\u57FA\uFF0C\u6216\u8005\u7528\u6240\u9700\u7684\u5B98\u80FD\u56E2\u66FF\u4EE3\u7FA7\u57FA\u3002 \uFF08\u53C2\u89C1\u8FF0\u56FE 1\uFF09\u8BE5\u53CD\u5E94\u5F97\u540D\u4E8E\u5176\u53D1\u73B0\u8005\uFF1A\u82F1\u56FD\u5316\u5B66\u5BB6\u3001\u8BFA\u8D1D\u5C14\u5956\u8005\u4E3B\u5FB7\u91CC\u514B\u00B7\u5DF4\u987F\u7235\u58EB (1918-1998) \u3002"@zh . . . "The Barton decarboxylation is a radical reaction in which a carboxylic acid is converted to a thiohydroxamate ester (commonly referred to as a Barton ester). The product is then heated in the presence of a radical initiator and a suitable hydrogen donor to afford the decarboxylated product. This is an example of a reductive decarboxylation. Using this reaction it is possible to remove carboxylic acid moieties from alkyl groups and replace them with other functional groups. (See Scheme 1) This reaction is named after its developer, the British chemist and Nobel laureate Sir Derek Barton (1918\u20131998)."@en . "The Barton decarboxylation is a radical reaction in which a carboxylic acid is converted to a thiohydroxamate ester (commonly referred to as a Barton ester). The product is then heated in the presence of a radical initiator and a suitable hydrogen donor to afford the decarboxylated product. This is an example of a reductive decarboxylation. Using this reaction it is possible to remove carboxylic acid moieties from alkyl groups and replace them with other functional groups. (See Scheme 1) This reaction is named after its developer, the British chemist and Nobel laureate Sir Derek Barton (1918\u20131998)."@en . "1097154299"^^ . "\u5DF4\u987F\u8131\u7FA7\u53CD\u5E94"@zh . . . . "Die Barton-Decarboxylierung ist eine Namensreaktion der organischen Chemie. Mit ihrer Hilfe k\u00F6nnen organische Reste z. B. von Carbons\u00E4urechloriden oder Carbons\u00E4uren abgespalten werden. Die Reaktion ist nach dem Chemiker und Nobelpreistr\u00E4ger Derek H. R. Barton benannt."@de . . . . . . . . . . . "October 2016"@en . . . . . "La Descarboxilaci\u00F3n de Barton es una reacci\u00F3n org\u00E1nica en la que previamente un \u00E1cido carbox\u00EDlico se convierte en una 1-aciloxipiridina (Funcionalmente es un \u00E9ster hidrox\u00E1mico com\u00FAnmente conocido como \u00E9ster de Barton). El producto se calienta en presencia de un iniciador de radicales y un donante de hidr\u00F3geno apropiado para completar la descarboxilaci\u00F3n reductiva del \u00E1cidos carbox\u00EDlico inicial.\u200B\u200B Esta reacci\u00F3n permite extraer el grupo carboxilo de un \u00E1cido de tal manera que el grupo alquilo sea sustituido con otros grupos funcionales.\u200B\u200B (ver esquema 1) Esta reacci\u00F3n debe su nombre al qu\u00EDmico brit\u00E1nico y Premio Nobel Derek Barton (1918-1998)."@es . "R\u00E9action de Barton-Motherwell"@fr . . . . "Barton decarboxylation"@en . . . "Die Barton-Decarboxylierung ist eine Namensreaktion der organischen Chemie. Mit ihrer Hilfe k\u00F6nnen organische Reste z. B. von Carbons\u00E4urechloriden oder Carbons\u00E4uren abgespalten werden. Die Reaktion ist nach dem Chemiker und Nobelpreistr\u00E4ger Derek H. R. Barton benannt."@de . . . "Barton decarboxylation"@en . . . . "InternetArchiveBot"@en . "Descarboxilaci\u00F3n de Barton"@es . "\u5DF4\u987F\u8131\u7FA7\u53CD\u5E94\u662F\u4E00\u79CD\u81EA\u7531\u57FA\u53CD\u5E94\uFF0C\u8BE5\u53CD\u5E94\u4E2D\u7FA7\u9178\u5148\u88AB\u8F6C\u5316\u4E3A\u786B\u4EE3\u5F02\u7F9F\u809F\u9178\u916F\uFF08\u901A\u5E38\u79F0\u4E3A\u5DF4\u987F\u916F\uFF09\u3002\u7136\u540E\u518D\u5728\u81EA\u7531\u57FA\u5F15\u53D1\u5242\u548C\u5408\u9002\u7684\u8FD8\u539F\u6027\u6C22\u4F9B\u4F53\u5B58\u5728\u4E0B\u5BF9\u4EA7\u7269\u8FDB\u884C\u52A0\u70ED\uFF0C\u8FDB\u800C\u53EF\u4EE5\u5F97\u5230\u8131\u7FA7\u540E\u7684\u4EA7\u7269\u3002 \u5DF4\u987F\u8131\u7FA7\u53CD\u5E94\u662F\u4E00\u79CD\u8FD8\u539F\u8131\u7FA7\u53CD\u5E94\u3002\u5229\u7528\u8BE5\u53CD\u5E94\uFF0C\u53EF\u4EE5\u4ECE\u6709\u673A\u7269\u4E2D\u8131\u53BB\u7FA7\u57FA\uFF0C\u6216\u8005\u7528\u6240\u9700\u7684\u5B98\u80FD\u56E2\u66FF\u4EE3\u7FA7\u57FA\u3002 \uFF08\u53C2\u89C1\u8FF0\u56FE 1\uFF09\u8BE5\u53CD\u5E94\u5F97\u540D\u4E8E\u5176\u53D1\u73B0\u8005\uFF1A\u82F1\u56FD\u5316\u5B66\u5BB6\u3001\u8BFA\u8D1D\u5C14\u5956\u8005\u4E3B\u5FB7\u91CC\u514B\u00B7\u5DF4\u987F\u7235\u58EB (1918-1998) \u3002"@zh . . .