. . . . . . . "In de organische chemie verwijst een ge\u00EBclipseerde conformatie (vaak aangeduid met de Engelse term eclipsed) naar een specifieke conformatie, waarbij de substituenten (veelal waterstofatomen) van 2 opeenvolgende koolstofatomen in een koolstofketen achter elkaar geschikt staan. Dit komt voornamelijk tot uiting bij de constructie van de Newmanprojectie. Daarbij is duidelijk te zien dat de substituenten elkaar sterisch hinderen (de tussen elk substituent bedraagt immers 0\u00B0). De elektronenwolken komen in elkaars vanderwaalsstraal te zitten, wat een afstoting veroorzaakt. Dat zorgt ervoor dat de ge\u00EBclipseerde conformatie een stuk onstabieler is dan de geschrankte conformatie (ongeveer 12,5 kJ/mol)."@nl . . . "8122"^^ . . . . . . "Eclipsed conformation"@en . "Eclipsed kallas den konformation mellan tv\u00E5 bundna atomer d\u00E4r torsionsvinkeln mellan substituenterna \u00E4r minimal. En molekyl som befinner sig i en eclipsed konformation besitter ofta en h\u00F6gre energi \u00E4n motsvarande staggered konformation. Detta beror p\u00E5 steriska interaktioner mellan substituenterna, som hamnar n\u00E4ra varandra. Denna kemirelaterade artikel saknar v\u00E4sentlig information. Du kan hj\u00E4lpa till genom att l\u00E4gga till den."@sv . "\u91CD\u306A\u308A\u5F62\u914D\u5EA7"@ja . "Eclipsed"@sv . . . . . . . . "\u0641\u064A \u0627\u0644\u0643\u064A\u0645\u064A\u0627\u0621 \u0627\u0644\u062A\u0634\u0643\u064A\u0644 \u0627\u0644\u0645\u0643\u0633\u0648\u0641 (\u0628\u0627\u0644\u0625\u0646\u062C\u0644\u064A\u0632\u064A\u0629: eclipsed)\u200F \u0623\u0648 \u0627\u0644\u0645\u062D\u062C\u0648\u0628 \u0644\u0623\u0646\u0647 \u0639\u0646\u062F \u0627\u0644\u0646\u0638\u0631 \u0644\u0645\u0631\u0643\u0628 \u0628\u0633\u064A\u0637 \u0643\u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u0645\u0646 \u0627\u0644\u062C\u0627\u0646\u0628 \u0627\u0644\u0645\u0648\u0627\u062C\u0647 \u0644\u0642\u0627\u0639\u062F\u0629 \u0631\u0628\u0627\u0639\u064A \u0627\u0644\u0623\u0648\u062C\u0647 \u0627\u0644\u0645\u0646\u062A\u0638\u0645 \u062A\u0628\u062F\u0648 \u0627\u0644\u0631\u0627\u0628\u0637\u0629 \u0628\u064A\u0646 \u0630\u0631\u062A\u064A \u0643\u0631\u0628\u0648\u0646 \u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u0645\u062D\u062C\u0648\u0628\u0629 \u0648\u0644\u0627 \u0646\u0631\u0627\u0647\u0627 \u0648\u0643\u0630\u0644\u0643 \u062A\u0628\u062F\u0648 \u0630\u0631\u0627\u062A \u0627\u0644\u0647\u064A\u062F\u0631\u0648\u062C\u064A\u0646 \u0627\u0644\u0645\u0631\u062A\u0628\u0637\u0629 \u0628\u0630\u0631\u0629 \u0627\u0644\u0643\u0631\u0628\u0648\u0646 \u0627\u0644\u0645\u0642\u0627\u0628\u0644\u0629 \u0644\u0644\u0630\u0631\u0629 \u0627\u0644\u062A\u064A \u0646\u0646\u0638\u0631 \u0625\u0644\u064A\u0647\u0627 \u0634\u0628\u0647 \u0645\u062D\u062C\u0648\u0628\u0629 \u0644\u0630\u0627 \u0641\u0647\u0648 \u0646\u0648\u0639 \u0645\u0646 \u0623\u0646\u0648\u0627\u0639 \u0627\u0644\u062A\u0634\u0643\u0644 \u0627\u0644\u0643\u064A\u0645\u064A\u0627\u0626\u064A \u064A\u062A\u0648\u0627\u062C\u062F \u0628\u064A\u0646 \u0630\u0631\u062A\u064A\u0646 \u0641\u064A \u0623\u064A \u0633\u0644\u0633\u0644\u0629 \u0645\u0641\u062A\u0648\u062D\u0629 \u0645\u0641\u0631\u062F\u0629 \u0627\u0644\u0631\u0627\u0628\u0637\u0629 \u0628\u064A\u0646 \u0645\u062F\u0627\u0631\u064A\u0646 \u0645\u0647\u062C\u0646\u064A\u0646 sp3 \u0648\u062A\u0635\u0644 \u0627\u0644\u0637\u0627\u0642\u0629 \u0641\u064A\u0647\u0627 \u0644\u0623\u0639\u0644\u0649 \u0645\u0633\u062A\u0648\u064A\u0627\u062A\u0647\u0627 \u0646\u0638\u0631\u0627 \u0644\u0648\u062C\u0648\u062F \u0627\u0644\u0625\u0639\u0627\u0642\u0629 \u0627\u0644\u0641\u0631\u0627\u063A\u064A\u0629."@ar . "Eclipsed kallas den konformation mellan tv\u00E5 bundna atomer d\u00E4r torsionsvinkeln mellan substituenterna \u00E4r minimal. En molekyl som befinner sig i en eclipsed konformation besitter ofta en h\u00F6gre energi \u00E4n motsvarande staggered konformation. Detta beror p\u00E5 steriska interaktioner mellan substituenterna, som hamnar n\u00E4ra varandra. Denna kemirelaterade artikel saknar v\u00E4sentlig information. Du kan hj\u00E4lpa till genom att l\u00E4gga till den."@sv . . . "1627862"^^ . . . . . "1124506926"^^ . . . . . "\u0645\u0643\u0633\u0648\u0641"@ar . . . "In de organische chemie verwijst een ge\u00EBclipseerde conformatie (vaak aangeduid met de Engelse term eclipsed) naar een specifieke conformatie, waarbij de substituenten (veelal waterstofatomen) van 2 opeenvolgende koolstofatomen in een koolstofketen achter elkaar geschikt staan. Dit komt voornamelijk tot uiting bij de constructie van de Newmanprojectie. Daarbij is duidelijk te zien dat de substituenten elkaar sterisch hinderen (de tussen elk substituent bedraagt immers 0\u00B0). De elektronenwolken komen in elkaars vanderwaalsstraal te zitten, wat een afstoting veroorzaakt. Dat zorgt ervoor dat de ge\u00EBclipseerde conformatie een stuk onstabieler is dan de geschrankte conformatie (ongeveer 12,5 kJ/mol). Dergelijke conformaties komen voor bij sp3-gehybridiseerde koolstofatomen, omdat er een vrije draaibaarheid ontstaat aan de sigma-binding. Bijgevolg kunnen een groot aantal conformaties worden aangenomen, waaronder de onstabiele ge\u00EBclipseerde conformatie."@nl . "Conformation \u00E9clips\u00E9e"@fr . "\u91CD\u306A\u308A\u5F62\u914D\u5EA7\uFF08\u304B\u3055\u306A\u308A\u304C\u305F\u306F\u3044\u3056\u3001\u82F1: Eclipsed conformation\uFF09\u306F\u3001\u96A3\u63A5\u3059\u308B\u539F\u5B50A,B\u4E0A\u306E2\u3064\u306E\u7F6E\u63DB\u57FAX,Y\u304C\u7A7A\u9593\u7684\u306B\u6700\u3082\u8FD1\u63A5\u3057\u3001X-A-B-Y\u306E\u306D\u3058\u308C\u89D2\u304C0\u5EA6\u3068\u306A\u308B\u914D\u5EA7\u3067\u3042\u308B\u3002\u3053\u306E\u3088\u3046\u306A\u914D\u5EA7\u306F\u30012\u3064\u306Esp3\u6DF7\u6210\u539F\u5B50\u304C\u5358\u7D50\u5408\u3067\u76F4\u9396\u72B6\u306B\u7E4B\u304C\u308B\u5834\u5408\u306B\u751F\u3058\u3001\u901A\u5E38\u306F\u914D\u5EA7\u30A8\u30CD\u30EB\u30AE\u30FC\u304C\u6700\u5927\u3068\u306A\u308B\u3002\u3053\u306E\u73FE\u8C61\u306F\u3001\u3057\u3070\u3057\u3070\u7ACB\u4F53\u969C\u5BB3\u306B\u3088\u3063\u3066\u8AAC\u660E\u3055\u308C\u308B\u304C\u3001\u5B9F\u969B\u306F\u8D85\u5171\u5F79\u306B\u8D77\u56E0\u3059\u308B\u3082\u306E\u3082\u3042\u308B\u3002 \u30CB\u30E5\u30FC\u30DE\u30F3\u6295\u5F71\u5F0F\u306E\u30A8\u30BF\u30F3\u306E\u4F8B\u3067\u306F\u3001\u70AD\u7D20-\u70AD\u7D20\u7D50\u5408\u306E\u5468\u308A\u306E\u56DE\u8EE2\u306F\u3001\u5B8C\u5168\u306B\u81EA\u7531\u3067\u306F\u306A\u304F\u3001\u30A8\u30CD\u30EB\u30AE\u30FC\u969C\u58C1\u304C\u5B58\u5728\u3059\u308B\u3002\u91CD\u306A\u308A\u5F62\u914D\u5EA7\u306E\u30A8\u30BF\u30F3\u5206\u5B50\u306F\u3001\u306D\u3058\u308C\u6B6A\u307F\u3092\u53D7\u3051\u3066\u304A\u308A\u3001\u306D\u3058\u308C\u5F62\u914D\u5EA7\u306B\u56DE\u8EE2\u3059\u308B\u969B\u306B\u306F\u3001\u7D0412.5 kJ/mol\u306E\u30A8\u30CD\u30EB\u30AE\u30FC\u3092\u653E\u51FA\u3059\u308B\u3002"@ja . . "In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X\u2013A\u2013B\u2013Y is 0\u00B0. Such a conformation can exist in any open chain, single chemical bond connecting two sp3-hybridised atoms, and it is normally a conformational energy maximum. This maximum is often explained by steric hindrance, but its origins sometimes actually lie in hyperconjugation (as when the eclipsing interaction is of two hydrogen atoms)."@en . . . "En st\u00E9r\u00E9ochimie, une conformation \u00E9clips\u00E9e est un cas de conform\u00E9rie d'un \u00E9difice mol\u00E9culaire dans laquelle les trois liaisons form\u00E9es par deux atomes ou groupes d'atomes attach\u00E9s \u00E0 deux atomes adjacents forment un angle de torsion \u00E9gal \u00E0 (ou voisin de) 0\u00B0 et, de ce fait, dans laquelle les atomes ou groupes apparaissent parall\u00E8les (conform\u00E8re \u00E9clips\u00E9)."@fr . . . . . "In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X\u2013A\u2013B\u2013Y is 0\u00B0. Such a conformation can exist in any open chain, single chemical bond connecting two sp3-hybridised atoms, and it is normally a conformational energy maximum. This maximum is often explained by steric hindrance, but its origins sometimes actually lie in hyperconjugation (as when the eclipsing interaction is of two hydrogen atoms). In order to gain a deeper understanding of eclipsed conformations in organic chemistry, it is first important to understand how organic molecules are arranged around bonds, as well as how they move and rotate. In the example of ethane, two methyl groups are connected with a carbon-carbon sigma bond, just as one might connect two Lego pieces through a single \u201Cstud\u201D and \u201Ctube\u201D. With this image in mind, if the methyl groups are rotated around the bond, they will remain connected; however, the shape will change. There are multiple possible results of this, such as different 3-dimensional shapes, also known as, \u201Cconformations\u201C, or, \u201Cconformational isomers\u201C, or sometimes, \u201Crotational isomers (rotamers)\u201D."@en . . . . . . "Ge\u00EBclipseerde conformatie"@nl . . . . "En st\u00E9r\u00E9ochimie, une conformation \u00E9clips\u00E9e est un cas de conform\u00E9rie d'un \u00E9difice mol\u00E9culaire dans laquelle les trois liaisons form\u00E9es par deux atomes ou groupes d'atomes attach\u00E9s \u00E0 deux atomes adjacents forment un angle de torsion \u00E9gal \u00E0 (ou voisin de) 0\u00B0 et, de ce fait, dans laquelle les atomes ou groupes apparaissent parall\u00E8les (conform\u00E8re \u00E9clips\u00E9)."@fr . "\u91CD\u306A\u308A\u5F62\u914D\u5EA7\uFF08\u304B\u3055\u306A\u308A\u304C\u305F\u306F\u3044\u3056\u3001\u82F1: Eclipsed conformation\uFF09\u306F\u3001\u96A3\u63A5\u3059\u308B\u539F\u5B50A,B\u4E0A\u306E2\u3064\u306E\u7F6E\u63DB\u57FAX,Y\u304C\u7A7A\u9593\u7684\u306B\u6700\u3082\u8FD1\u63A5\u3057\u3001X-A-B-Y\u306E\u306D\u3058\u308C\u89D2\u304C0\u5EA6\u3068\u306A\u308B\u914D\u5EA7\u3067\u3042\u308B\u3002\u3053\u306E\u3088\u3046\u306A\u914D\u5EA7\u306F\u30012\u3064\u306Esp3\u6DF7\u6210\u539F\u5B50\u304C\u5358\u7D50\u5408\u3067\u76F4\u9396\u72B6\u306B\u7E4B\u304C\u308B\u5834\u5408\u306B\u751F\u3058\u3001\u901A\u5E38\u306F\u914D\u5EA7\u30A8\u30CD\u30EB\u30AE\u30FC\u304C\u6700\u5927\u3068\u306A\u308B\u3002\u3053\u306E\u73FE\u8C61\u306F\u3001\u3057\u3070\u3057\u3070\u7ACB\u4F53\u969C\u5BB3\u306B\u3088\u3063\u3066\u8AAC\u660E\u3055\u308C\u308B\u304C\u3001\u5B9F\u969B\u306F\u8D85\u5171\u5F79\u306B\u8D77\u56E0\u3059\u308B\u3082\u306E\u3082\u3042\u308B\u3002 \u30CB\u30E5\u30FC\u30DE\u30F3\u6295\u5F71\u5F0F\u306E\u30A8\u30BF\u30F3\u306E\u4F8B\u3067\u306F\u3001\u70AD\u7D20-\u70AD\u7D20\u7D50\u5408\u306E\u5468\u308A\u306E\u56DE\u8EE2\u306F\u3001\u5B8C\u5168\u306B\u81EA\u7531\u3067\u306F\u306A\u304F\u3001\u30A8\u30CD\u30EB\u30AE\u30FC\u969C\u58C1\u304C\u5B58\u5728\u3059\u308B\u3002\u91CD\u306A\u308A\u5F62\u914D\u5EA7\u306E\u30A8\u30BF\u30F3\u5206\u5B50\u306F\u3001\u306D\u3058\u308C\u6B6A\u307F\u3092\u53D7\u3051\u3066\u304A\u308A\u3001\u306D\u3058\u308C\u5F62\u914D\u5EA7\u306B\u56DE\u8EE2\u3059\u308B\u969B\u306B\u306F\u3001\u7D0412.5 kJ/mol\u306E\u30A8\u30CD\u30EB\u30AE\u30FC\u3092\u653E\u51FA\u3059\u308B\u3002"@ja . . "\u0641\u064A \u0627\u0644\u0643\u064A\u0645\u064A\u0627\u0621 \u0627\u0644\u062A\u0634\u0643\u064A\u0644 \u0627\u0644\u0645\u0643\u0633\u0648\u0641 (\u0628\u0627\u0644\u0625\u0646\u062C\u0644\u064A\u0632\u064A\u0629: eclipsed)\u200F \u0623\u0648 \u0627\u0644\u0645\u062D\u062C\u0648\u0628 \u0644\u0623\u0646\u0647 \u0639\u0646\u062F \u0627\u0644\u0646\u0638\u0631 \u0644\u0645\u0631\u0643\u0628 \u0628\u0633\u064A\u0637 \u0643\u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u0645\u0646 \u0627\u0644\u062C\u0627\u0646\u0628 \u0627\u0644\u0645\u0648\u0627\u062C\u0647 \u0644\u0642\u0627\u0639\u062F\u0629 \u0631\u0628\u0627\u0639\u064A \u0627\u0644\u0623\u0648\u062C\u0647 \u0627\u0644\u0645\u0646\u062A\u0638\u0645 \u062A\u0628\u062F\u0648 \u0627\u0644\u0631\u0627\u0628\u0637\u0629 \u0628\u064A\u0646 \u0630\u0631\u062A\u064A \u0643\u0631\u0628\u0648\u0646 \u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u0645\u062D\u062C\u0648\u0628\u0629 \u0648\u0644\u0627 \u0646\u0631\u0627\u0647\u0627 \u0648\u0643\u0630\u0644\u0643 \u062A\u0628\u062F\u0648 \u0630\u0631\u0627\u062A \u0627\u0644\u0647\u064A\u062F\u0631\u0648\u062C\u064A\u0646 \u0627\u0644\u0645\u0631\u062A\u0628\u0637\u0629 \u0628\u0630\u0631\u0629 \u0627\u0644\u0643\u0631\u0628\u0648\u0646 \u0627\u0644\u0645\u0642\u0627\u0628\u0644\u0629 \u0644\u0644\u0630\u0631\u0629 \u0627\u0644\u062A\u064A \u0646\u0646\u0638\u0631 \u0625\u0644\u064A\u0647\u0627 \u0634\u0628\u0647 \u0645\u062D\u062C\u0648\u0628\u0629 \u0644\u0630\u0627 \u0641\u0647\u0648 \u0646\u0648\u0639 \u0645\u0646 \u0623\u0646\u0648\u0627\u0639 \u0627\u0644\u062A\u0634\u0643\u0644 \u0627\u0644\u0643\u064A\u0645\u064A\u0627\u0626\u064A \u064A\u062A\u0648\u0627\u062C\u062F \u0628\u064A\u0646 \u0630\u0631\u062A\u064A\u0646 \u0641\u064A \u0623\u064A \u0633\u0644\u0633\u0644\u0629 \u0645\u0641\u062A\u0648\u062D\u0629 \u0645\u0641\u0631\u062F\u0629 \u0627\u0644\u0631\u0627\u0628\u0637\u0629 \u0628\u064A\u0646 \u0645\u062F\u0627\u0631\u064A\u0646 \u0645\u0647\u062C\u0646\u064A\u0646 sp3 \u0648\u062A\u0635\u0644 \u0627\u0644\u0637\u0627\u0642\u0629 \u0641\u064A\u0647\u0627 \u0644\u0623\u0639\u0644\u0649 \u0645\u0633\u062A\u0648\u064A\u0627\u062A\u0647\u0627 \u0646\u0638\u0631\u0627 \u0644\u0648\u062C\u0648\u062F \u0627\u0644\u0625\u0639\u0627\u0642\u0629 \u0627\u0644\u0641\u0631\u0627\u063A\u064A\u0629. \u0648\u0641\u064A \u0645\u062B\u0627\u0644 \u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u064A\u0638\u0647\u0631 \u0645\u0633\u0642\u0637 \u0646\u064A\u0648\u0645\u0627\u0646 \u0623\u0646 \u0627\u0644\u062F\u0648\u0631\u0627\u0646 \u062D\u0648\u0644 \u0631\u0627\u0628\u0637\u0629 C-C \u0644\u064A\u0633 \u0643\u0627\u0645\u0644 \u0627\u0644\u062D\u0631\u064A\u0629 \u0648\u0644\u0643\u0646 \u062A\u0648\u062C\u062F \u062D\u0648\u0627\u062C\u0632 \u0637\u0627\u0642\u0629. \u0648\u062C\u0632\u064A\u0621 \u0627\u0644\u0625\u064A\u062B\u0627\u0646 \u0641\u064A \u0627\u0644\u062A\u0634\u0643\u0644 \u0627\u0644\u0645\u062D\u062C\u0648\u0628 \u064A\u0639\u0627\u0646\u064A \u0645\u0646 \u0648\u0628\u062D\u062F\u0648\u062B \u062F\u0648\u0631\u0627\u0646 \u062D\u0648\u0644 \u0631\u0627\u0628\u0637\u0629 C-C \u0641\u0625\u0646\u0647 \u0639\u0646\u062F \u062D\u062F\u0648\u062B \u0627\u0644\u062F\u0648\u0631\u0627\u0646 \u0628\u0639\u062F \u0627\u0644\u062A\u0634\u0643\u0644 \u0627\u0644\u0645\u0643\u0633\u0648\u0641 \u062A\u0646\u0637\u0644\u0642 \u0645\u0642\u062F\u0627\u0631\u0647\u0627 12.5 \u0643\u064A\u0644\u0648 \u062C\u0648\u0644/\u0645\u0648\u0644."@ar .