Electroextraction (EE) is a sample enrichment technique that focuses charged analytes from a large volume of one phase into a small volume of aqueous phase through the application of an electric current. The technique was originally developed as a separation technique for chemical engineering, but has since been coupled to capillary electrophoresis and liquid chromatography–mass spectrometry as a means of improving limits of detection, analysis time, and selectivity. The use of EE-CE has made capillary electrophoresis more applicable to use in the pharmaceutical industry.
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